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You should bed new pads in everytime you replace them.
From Stoptech:
Bedding in: There are two types of "bedding in" with regard to brakes:
1. Bedding of the friction material. All friction materials contain volatile elements used as binders. In the initial thermal cycling of the material these volatiles boil off, forming a gaseous layer between the friction material and the brake. A bedded pad will exhibit a layer of discolored material from 1.5 to 3 mm thick.
2. Bedding of the disc. Before using a new disk, all machining and preservative oils must be completely removed following the disc manufacturer's recommendations. Usually it involves washing with soap and water or using one of the proprietary "brake clean" compounds. The disc should then be mounted and checked for run out. It should be bedded in with a number of moderate stops with lots of cool off time between stops, gradually increasing the severity of the stops until the entire surface of the disc is evenly discolored. This will prevent thermal shock, distortion and the formation of "hot spots" (regional deposition of pad material which results in a permanent transformation of the cast iron underneath the deposit) and ensure maximum disk life.
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